From XML Publisher Administrator responsibility, create a Data Definition and Template and make sure that you have defined ARXSGP in the code field. Then go to Receivables Manager, run the Statement Generation Program. Navigate to Requests > Run > XML Report Publisher and choose the Statement run concurrent request id that just completed from the Report Request LOV. Select your Template and choose your output and the statement will be printed.
This is the two step process to print an XML generated Statement as there is currently no 1 step process. Statements do not use the same job submission program as other Receivables reports.